Carbon fiber has become a revolutionary material in advanced manufacturing owing to its outstanding specific streng...
Carbon fiber has become a revolutionary material in advanced manufacturing owing to its outstanding specific strength, specific modulus, low density, excellent wear resistance and corrosion resistance. As an important engineering plastic, polyamide 6 (PA6) has been continuously improved in performance and application scope with technological progress. By compounding carbon fiber with PA6, a new type of high‑strength, lightweight and corrosion‑resistant material can be prepared by combining the advantages of both components, which shows broad application prospects in automotive, aerospace, medical devices and other fields, and is also of great significance to environmental protection and sustainable development.

This study systematically investigated the effects of different carbon fiber types (T300 and T700) and fiber content on the mechanical properties of PA6 composites. In the experiment, two types of 12K carbon fibers (T300 and T700), with and without sizing agent, were blended with PA6 using a twin‑screw extruder to prepare pellets, and test specimens were manufactured by injection molding. The actual carbon fiber content was determined by thermogravimetric analysis, ranging from approximately 10 wt% to 30 wt%.
Mechanical test results show that the addition of carbon fiber significantly improves the tensile strength, flexural strength and flexural modulus of PA6. Neat PA6 exhibits a tensile strength of about 70 MPa, flexural strength of about 100 MPa, and flexural modulus of only 2.4 GPa. When reinforced with about 30 wt% T300 carbon fiber, the composite reaches a tensile strength of 166 MPa, 236.6% higher than that of neat PA6; the flexural strength is 224 MPa, increased by 229.6%; and the flexural modulus is 14.6 GPa, six times that of pure PA6. As for the notched impact strength, although it decreases after carbon fiber incorporation compared with neat PA6, it shows an upward trend with increasing fiber content, reaching a maximum of 7.18 kJ/m².

Comparison between T300 and T700 reveals that T700 reinforced composites possess superior overall performance, mainly due to the higher filament strength and modulus of T700, as well as better fiber length retention during processing. Notably, the sizing agent exerts different influences on the two fibers. For T300, sizing treatment improves the interfacial bonding between fiber and matrix, leading to better composite properties than unsized T300. For T700, owing to its smooth surface and inherently excellent performance, no obvious performance difference is observed between sized and unsized samples.
Microstructural morphology was observed via scanning electron microscopy (SEM) on impact fracture surfaces. The fracture surface of neat PA6 shows obvious wrinkles, while the fracture surfaces of composites become rougher with increased fiber content, accompanied by more fiber pull‑out and crack deflection. The fiber‑matrix interfacial wetting is satisfactory, and the resin can effectively encapsulate the fibers, which facilitates stress transfer. With increasing fiber content, fiber‑to‑fiber contact and interaction are enhanced, accompanied by partial fiber aggregation and entanglement.

Fiber length distribution was studied by microscopic observation of carbon residues after thermogravimetric analysis. The results show that the fiber length approximates a Gaussian distribution, mainly in the range of 100–300 μm, with some ultra‑long fibers exceeding 500 μm. Interestingly, although the average fiber length decreases under screw shearing as fiber content increases, the mechanical properties continue to rise, indicating that the effect of fiber content outweighs that of fiber length within this range. The retained length of T700 fibers in the matrix is generally longer than that of T300, which also contributes to its superior reinforcing efficiency.
Thermal performance analysis shows that carbon fiber has little effect on the thermal decomposition temperature of PA6. The initial decomposition temperature is about 403 °C and the maximum decomposition temperature is about 470 °C, while carbon fiber increases the char yield to approximately 28%. Differential scanning calorimetry (DSC) indicates that carbon fiber, acting as a heterogeneous nucleating agent, provides more nucleation sites, raises the crystallization temperature from 181.4 °C to about 185 °C, and accelerates the crystallization rate. Meanwhile, it restricts crystal growth, leading to a decrease in crystallinity from 44.83% for neat PA6 to about 30%.
In summary, this study confirms that carbon fiber is a highly efficient reinforcement for PA6, and the optimal comprehensive mechanical properties are obtained at about 30 wt% fiber loading. T700 carbon fiber presents better reinforcing effect due to its higher intrinsic strength and better length retention. Proper fiber length distribution, strong interfacial bonding and favorable fiber orientation are key factors for achieving high performance. This work provides theoretical guidance and practical reference for the preparation and application of high‑performance carbon fiber reinforced polyamide 6 composites.